St. Paul Regional Water Services and the University of Minnesota pilot water treatment plant project.

Saint Paul Regional Water Services (SPRWS) provides potable water to approximately 450,000 people in Saint Paul, Minnesota and surrounding suburbs. To continue to provide a safe and reliable water supply and to address potential future water quality challenges, improvements to the water treatment plant (WTP) were investigated. The potential improvements considered include a new softening process and the addition of ozone or advanced oxidation process (AOP) technology ahead of the existing biologically-active activated carbon (BAC) filters. To investigate these treatment alternatives, a pilot study was conducted from March 2021 - March 2022.

The results of this study suggest that the addition of ozone is beneficial as it provides improved removal of a variety of trace organic contaminants, reduced formation of regulated disinfection byproduct precursors (DBPs) and N-nitrosodimethlyamine (NDMA), and does not have any negative impacts on filter performance (i.e., particle removal, filter run time). We observed no added benefits of using AOP versus ozone alone, likely because the pH conditions in recarbonated water already result in production of hydroxyl radicals with just ozone, so addition of hydrogen peroxide is not recommended at this time. The increased release of heterotrophic plate count (HPC) bacteria from the filters fed ozonated water and the higher assimilable organic carbon (AOC) concentrations following disinfection are potential concerns that likely can be effectively managed via proper disinfection and maintenance of a chloramine residual in the distribution system. Finally, replacing the granular activated carbon (GAC) in the filters when the new ozone system comes online would be beneficial in reducing exposure to trace organic contaminants that can desorb from the filter media at low levels for an indeterminant amount of time.

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Project Two